Oh okay, so in benzene the carbon to carbon bonds are all the same length, and that length is in between the length of C-C and C=C bonds?.. 0.139 according to the book.. What about the Kekule model, what does that say about the bond lengths, and what about C-C and C=C bond lengths in general?
Can someone explain the part about carbon-carbon bond lengths in: Kekule's model Benzene
And also can you explain the actual lengths of C-C and C=C bonds in regular compounds, like alkanes/alkenes.
The book is a little on this part, for me atleast.
Thanks a bunch!
If the actual structure of benzene were to be alternating double C=C and single C-C bonds, like in the Kekule structure, you would expect there to be two different bond lengths in benzene.
However, spectroscopic studies show that there is only one C-C bond length.
In benzene C-C is 0.139 nm
normal C-C bonds are 0.154 nm and C=C bonds are 0.134nm
hence the bond length in benzene is intermediate between single and double bonds.
Can someone explain the part about carbon-carbon bond lengths in: Kekule's model Benzene
And also can you explain the actual lengths of C-C and C=C bonds in regular compounds, like alkanes/alkenes.
The book is a little on this part, for me atleast.
Thanks a bunch!
The carbon carbon bond lengths in Kekule's model are in between the lengths of an alkane and and alkene's bond length. This is unusual because Kekule suggested that there are 3 double bonds and 3 single bonds, therefore you would EXPECT there to be 3 bonds the same size and the other 3 bonds the same size but this isn't the case as all 6 c-c bonds in benzene are in between the length of an alkane and alkene's bond length.