The Student Room Group

Why do larger molecules have higher entropies?

Which of these solid substances is likely to have the greatest standard entropy? Use of
the data booklet is not required.

A SnO
B SnO2
C SnBr2
D SnBr4

the answer is D but to me this is counter intuitive as SnO will form the weakest Intermolecular forces so will be less ordered and thus have higher entropy?

Please Help
The bigger the molecule the more internal parts it has (protons, neutrons, electrons) so the more different arrangements it can exist in => more disorder => higher entropy
Reply 2
cheers, I am assuming that External state, i.e. (Gas>Liquid>Solid) has a greater effect than size?
Original post by OSharp
cheers, I am assuming that External state, i.e. (Gas>Liquid>Solid) has a greater effect than size?


Yes, but these are all solids at 298 K :smile:

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