ligand substitution

Chemistry discussion, revision, exam and homework help.

This thread is sponsored by:
Announcements Posted on
Important: please read these guidelines before posting about exams on The Student Room 28-04-2013
Sign in to Reply
  1. asaaal's Avatar
    • Benevolent Member
    • Posts: 738
    ligand substitution
    [cr(h20)3+] and excess ammonia are added together. suggest the equation

    i put:
    [Cr(H2O)6]3+ + 4NH3 --> [Cr(NH3)4(H2O)2]3+ + 4H2O

    but its wrong, the answer is:
    [Cr(H2O)6]3+ + 6NH3 --> [Cr(NH3)6]3+ + 6H2O

    why is my answer wrong?
  2. YB101's Avatar
    • Exalted and Worshipped Member
    • Posts: 1,203
    Re: ligand substitution
    (Original post by asaaal)
    [cr(h20)3+] and excess ammonia are added together. suggest the equation

    i put:
    [Cr(H2O)6]3+ + 4NH3 --> [Cr(NH3)4(H2O)2]3+ + 4H2O

    but its wrong, the answer is:
    [Cr(H2O)6]3+ + 6NH3 --> [Cr(NH3)6]3+ + 6H2O

    why is my answer wrong?
    Your answer is right! Are you reading the mark scheme? On the right hand side it should say "allow [Cr(H2O)6]3+ + 4NH3 --> [Cr(NH3)4(H2O)2]3+ + 4H2O "

    I remember doing this question and thinking I was wrong however I recall being taught it that way!
  3. asaaal's Avatar
    • Benevolent Member
    • Posts: 738
    Re: ligand substitution
    (Original post by YB101)
    Your answer is right! Are you reading the mark scheme? On the right hand side it should say "allow [Cr(H2O)6]3+ + 4NH3 --> [Cr(NH3)4(H2O)2]3+ + 4H2O "

    I remember doing this question and thinking I was wrong however I recall being taught it that way!
    oh so it does !
    Thank you
  4. EierVonSatan's Avatar
    • PS Helper
    • TSR Royalty
    • Location: UK
    • Posts: 21,065
    Re: ligand substitution
    I like how they ''allow'' the correct answer :p:

    edit: wait, no, I need to go to the opticians Cr isn't Cu :shifty:
    Last edited by EierVonSatan; 25-05-2012 at 12:35.
  5. asaaal's Avatar
    • Benevolent Member
    • Posts: 738
    Re: ligand substitution
    (Original post by EierVonSatan)
    I like how they ''allow'' the correct answer :p:
    the mark scheme is so stupid. I hope i get a good examiner marking my paper though
    last year for AS i was 1 mark off an A so i got my paper back and he or she had marked my answer '69.2% yield' wrong :|
    how can you mark a number wrong :| it takes absolutely no personal opinion and its so objective... theyd missed out 6 marks over all in that one paper :|
  6. YB101's Avatar
    • Exalted and Worshipped Member
    • Posts: 1,203
    Re: ligand substitution
    (Original post by EierVonSatan)
    I like how they ''allow'' the correct answer :p:
    I know! I seriously despise both the biology and chemistry mark schemes -.-
  7. thegodofgod's Avatar
    • TSR Legend
    • Location: London
    • Posts: 11,061
    Re: ligand substitution
    (Original post by EierVonSatan)
    I like how they ''allow'' the correct answer :p:
    In AQA they don't mention anything about the diaqua complex; they only mention the purple hexaammine complex
Sign in to Reply
Share this discussion:  
Article updates
Moderators

We have a brilliant team of more than 60 volunteers looking after discussions on The Student Room, helping to make it a fun, safe and useful place to hang out.

Reputation gems:
The Reputation gems seen here indicate how well reputed the user is, red gem indicate negative reputation and green indicates a good rep.
Post rating score:
These scores show if a post has been positively or negatively rated by our members.