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Read through your CV and application form (and anything else you've sent them). They will have read this, so may ask further questions on it. They're not going to say "regarding paragraph 4, can you expand?" but if you've said you've read something or learnt something they may want to talk about it.
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Learn dates. I used to interview, although not for healthcare, and it always looked dodgy if people didn't know when they claimed to have done things. You don't need exact dd/mm/yy, but if you can't tell me that you did your GCSEs in 2002 I will think you're making it up.
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Take in some examples of things you did. You don't want to over-prepare and be word perfect, but if you know that you can talk about the time you were in a marching band and use it as an example of team work then it will help to eliminate nervous pauses.
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Look at the person specification. This should be on the NHS jobs website, but if not then ask them for a copy. This will tell you all the questions they will ask! Obviously it won't beexact, but it will tell you the areas they're looking for. If it says "must have an awareness of good hygiene" then you'll be asked about that. If it says "must be able to work under pressure" then you'll need to demonstrate that.
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Turn up early. Care homes can be big, and many have door codes - so it might take longer to get in than you think.
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Think about what the patients/care users want. If it's a specific type of care home (eg for old people, cancer patients etc) then it might help to look at a relevant charity's website - you might get tips on how to treat that kind of patient. For example, if your care home has people with dementia, they do not like being referred to as "demented" or "suffering" with dementia. Similarly, "handicapped" has now fallen out of use. You don't want to be offensive even if it was unintentional.
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Don't wear high heels.This might just be personal preference, but I always think high heels show you're not prepared for the nature of the job. Low heels are fine, but leave the stilettosto Mrs Beauchamp.
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Have a look on the CQC website to see if they have inspected the care home recently. You might be able to comment that they were praised for always having sufficient supplies of personal protective equipment in the home.