becasue Bromine is a group 7 halogen, it's found as Br2, similar to chlorine Cl2, and Iodine, I2.
Hence, in the mass spectrometer because either atom could be either isotope, for Br2 there are 3 combinations of atoms, 79-79, 79-81, or 81-81.
Furthermore, the + is because the molecule is ionised in the mass spectrometer.
It doesn't matter about 79-81 vs 81-79 because it's the same molecule but flipped.
Hope this helps, feel free to ask for more explanation if required