k = 6.51 x 10^-3 mol-1dm3 T = 300K A = 2.57 x 10^10 mol-1dm3 R = 8.31 JK-1mol-1
Using lnk = lnA - Ea / RT find Ea in kJmol-1
I did:
ln6.51 x 10^-3 = ln2.57 x 10^10 - Ea / 8.31 x 300 -12550.79... = ln2.57 x 10^10 - Ea Ea = ln2.57 x 10^10 + 12550.79... Ea = 12574.768... Jmol-1 Ea = 12.6 kJmol-1 (3.s.f)
k = 6.51 x 10^-3 mol-1dm3 T = 300K A = 2.57 x 10^10 mol-1dm3 R = 8.31 JK-1mol-1
Using lnk = lnA - Ea / RT find Ea in kJmol-1
I did:
ln6.51 x 10^-3 = ln2.57 x 10^10 - Ea / 8.31 x 300 -12550.79... = ln2.57 x 10^10 - Ea Ea = ln2.57 x 10^10 + 12550.79... Ea = 12574.768... Jmol-1 Ea = 12.6 kJmol-1 (3.s.f)
I also got 73.2kj/mol. Show us the steps of your rearranging.
ln6.51 x 10^-3 = ln2.57 x 10^10 - Ea / 8.31 x 300 -12550.79... = ln2.57 x 10^10 - Ea Ea = ln2.57 x 10^10 + 12550.79... Ea = 12574.768... Jmol-1 Ea = 12.6 kJmol-1 (3.s.f)
ln6.51 x 10^-3 = ln2.57 x 10^10 - Ea / 8.31 x 300 -12550.79... = ln2.57 x 10^10 - Ea Ea = ln2.57 x 10^10 + 12550.79... Ea = 12574.768... Jmol-1 Ea = 12.6 kJmol-1 (3.s.f)
In step 2, you forgot to times In(2.57 x 10^10) by (8.31x300).
ln6.51 x 10^-3 = ln2.57 x 10^10 - Ea / 8.31 x 300 -12550.79... = ln2.57 x 10^10 - Ea
You went wrong at this part. You multiplied the whole left side by RT when it is only EA/RT on the right hand side, not (lnA-Ea/RT) but rather lnA-(Ea/RT).
You went wrong at this part. You multiplied the whole left side by RT when it is only EA/RT on the right hand side, not (lnA-Ea/RT) but rather lnA-(Ea/RT).