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OCR A Chemistry F322 Chains, Energy and Resources Thu 19 Jan 2012

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Original post by zainahmed
Im struggling with halogenoalkanes what does evryone know about them?


As you go down group 7, the C-halogen bond becomes weaker, as the polarity decreases due to the halogen being less electronegative and therefore the bond enthalpy decreases. This is why the rate of hydrolysis increases from Cl to I halogenoalkanes; the bond breaks (by heterolytic fission) more easily.
Original post by dee11
why does 1-Iodopropane hydrolyed faster than 1-bromopropane?

starting off pretty easy:biggrin:


See post below :biggrin:.
Reply 102
Original post by splendidsun
nooope :smile: but i think the general definition for biofuels is fuels that have been made from recently living materials like plants


ahhh right okay, ive noted that thanks :smile:
Original post by zainahmed
Im struggling with halogenoalkanes what does evryone know about them?


They are alkanes with atleast one hydrogen on the carbon chain substituted with a halogen (in order of decreasing electronegativity: Cl, Br, I)

Due to the difference in electronegativity between the carbon and halogen, a dipole is established across the bond which deems it prone to attack by nucleophilic substitution. This explains why halogenoalkanes can take part in hydrolysis reactions, the OH ions being the nucleophiles due to the presence of a lone pair.
Original post by dee11
why does 1-Iodopropane hydrolyed faster than 1-bromopropane?

starting off pretty easy:biggrin:


Weaker bond, less energy required to break
Reply 105
Original post by zainahmed
the amount of radiation it can absord i think its infared radiation? correct me if am wrong

and its relative concentration in the atmosphere

the amount a gas has and effect is measured by its GWP global warming potential score


yeahh, pretty much. Its the gases ability to absorb IR and the concentraion of the gas in the atmosphere like you said
Reply 106
Original post by splendidsun
Weaker bond, less energy required to break


yeah your right, but i think you'd have to mention weaker Bond enthalpy between C-I somewhere too to get the 2 marks

you've got the idea though
Reply 107
Do the molar quantities effect the atom economy?
Original post by dee11
yeah your right, but i think you'd have to mention weaker Bond enthalpy between C-I somewhere too to get the 2 marks

you've got the idea though


yh, true that


what are the uses of crude oil fractions?
Reply 109
Original post by nffc-b
Do the molar quantities effect the atom economy?


accidently pressed negative rating sorry

and yeh i think it does cos it involves molecular mass not sure??
What is the environmental damage caused by

i) Nitrogen Oxide
ii) Nitrogen Dioxide
Reply 111
2 reasons why enthalpy changes of cumbustion determined experimentally may not match the standard enthalpy values?
Reply 112
Original post by zainahmed
accidently pressed negative rating sorry

and yeh i think it does cos it involves molecular mass not sure??


Haha its cool bro, and I think it does aswell, but in all the past papers its always been just 1mole of each when asking for the atom economy so I dunno
Reply 113
anyone care to explain what halogens have go to do with cfcs
Original post by dee11
2 reasons why enthalpy changes of cumbustion determined experimentally may not match the standard enthalpy values?


Heat energy released to surroundings

Incomplete combustion may have taken place

(+ standard conditions may not have been met)
Reply 115
Original post by dee11
2 reasons why enthalpy changes of cumbustion determined experimentally may not match the standard enthalpy values?


Loss of heat to the surroundings
Incomplete combustion
May not be standard conditions
Reply 116
Original post by splendidsun
yh, true that


what are the uses of crude oil fractions?


you mean like fractional distilaton?
Original post by dee11
you mean like fractional distilaton?


yh
Reply 118
Original post by zainahmed
anyone care to explain what halogens have go to do with cfcs


CFCs contain halogens
Original post by dee11
2 reasons why enthalpy changes of cumbustion determined experimentally may not match the standard enthalpy values?


Sorry, I just had to point out the inredibly awesome typo :biggrin:.

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