Definition of D-block element!
Chemistry discussion, revision, exam and homework help.
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Definition of D-block element!
So here is what MS says:
d block: (Ni
‘d’ is highest energy sub-shell/orbital
But I thought 4s has has the highest energy!
Someone shed some light on this plss
also I dunno the difference between subshell and orbital and shell!
if there is any good website I could read about it -pls link me up
+repLast edited by arvin_infinity; 06-05-2012 at 18:26. -
Re: Definition of D-block element!+rep(Original post by EierVonSatan)
subshell = the s, p, d, f subshells you are familiar with
orbital = holds 2 electrons of opposite spin
So shell > subsell > orbital
you changed your avatar..only just noticed!
Here is another definition off MS:
Transition element: has an ion with an
incomplete/partially-filled d sub-shell/orbital
it looks as though sub-shell and orbital are the same thing! that's why I got confused
So maybe I ask this question: is it like 5 orbitals in d sub-shell and then the number of e inside those orbitals can be between 2,3,4,...,9 (so not 1 and 10 and therefore incomplete if you see what I mean)
So just to clarify: if we look at 4s2Shell = distinguished by principle quantum number n (the big numbers in 1s2, 3d5)
4 is the quantom number
s is the subshell
and s contains one orbital with 2 e
Oo I see why I was confused now! I was thinking 4s lose electrons first so must be the highest energy sub-shell4s fills before 3d, so it must be lower in energy
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Re: Definition of D-block element!I'm often changing it. I get bored easy

If you have an unfilled d-orbital then you must also have an unfilled d-subshell since orbitals make up the subshellHere is another definition off MS:
Transition element: has an ion with an
incomplete/partially-filled d sub-shell/orbital
it looks as though sub-shell and orbital are the same thing! that's why I got confused
It can be 1 but not 10, because 10 is filled and 0 is unfilled. 1-9 is partially filledSo maybe I ask this question: is it like 5 orbitals in d sub-shell and then the number of e inside those orbitals can be between 2,3,4,...,9 (so not 1 and 10 and therefore incomplete if you see what I mean)
So just to clarify: if we look at 4s2
4 is the quantom number
s is the subshell
and s contains one orbital with 2 e
It's bit involved but yes, electrons fill the 4s first but are also lost first when forming ions.Oo I see why I was confused now! I was thinking 4s lose electrons first so must be the highest energy sub-shell -
Re: Definition of D-block element!(Original post by EierVonSatan)
If you have an unfilled d-orbital then you must also have an unfilled d-subshell since orbitals make up the subshell


I feel like changing mine too..but just can't be bothered to wait for uploading the pages and ..I'm often changing it. I get bored easy
Is it right thinking e configuration is actually in an ascending order of energyIt's bit involved but yes, electrons fill the 4s first but are also lost first when forming ions.
1s,2s,2p,3s,3..4s,3d,4p-d-f
yh my bad I was meant to say 1-9It can be 1 but not 10, because 10 is filled and 0 is unfilled. 1-9 is partially filled
But back to my question is this right thinking those "boxes" with opposites spin are the orbitals! so e.g. d sub-shell has 5 orbitals?! -
Re: Definition of D-block element!You won't be asked about any element heavier than Kr. So you don't have to worry about f orbitals since things get messy and the relative energies are not so easy to determine.(Original post by arvin_infinity)
Is it right thinking e configuration is actually in an ascending order of energy
1s,2s,2p,3s,3..4s,3d,4p-d-f
Yep, the boxes with arrows going up and down are representations of orbitals.yh my bad I was meant to say 1-9
But back to my question is this right thinking those "boxes" with opposites spin are the orbitals! so e.g. d sub-shell has 5 orbitals?!
s subshell = 1 orbital
p subshell = 3 orbitals
d subshell = 5 orbitals
f subshell = 7 orbitals
and so on...
‘d’ is highest energy sub-shell/orbital 