A2 Chemistry - Buffer Solutions help!!!

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  1. moorbre's Avatar
    • Exalted Member
    • Posts: 385
    A2 Chemistry - Buffer Solutions help!!!
    I keep failing these questions.....completely
    My examining board is OCR if that helps

    Can someone please explain
    1. How are they formed ?
    2. How to form their equillibruim equations?
    3. How they control added acid alkali?

    Thanks guys much appreciated
  2. Dreamweaver's Avatar
    • Benevolent Member
    • Location: London
    • Posts: 839
    Re: A2 Chemistry - Buffer Solutions help!!!
    Formation:

    They are formed from a weak acid and a salt of the weak acid. This means there is a high concentration of the weak acid and its conjugate base (provided by the salt of the weak acid).

    Equation is simply the dissociation of a weak acid:

    HA(aq) \underset{0}{\overset{a}{\rightl  eftarrows}}A^-(aq)+H^+(aq)

    For added acid:

    Concentration of H+ is increased. This reacts with the conjugate base forming the weak acid. Therefore, equilibrium shifts to the LHS.

    For added alkali:

    Concentration of the alkali is increased. This reacts with the small amount of H+ in the solution, thereby removing it. The weak acid dissociates to replace lost H+ ions. Equilibrium shifts to the RHS.
    Last edited by Dreamweaver; 04-06-2012 at 14:53.
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