The relative atomic mass of an element is an average defined by the abundance of it's isotopes. For Copper's Ar to be less than 64, the Cu-63 isotope must be more abundant than the Cu-65 isotope.
It's quite easy; the relative atomic mass is less than 64 meaning there are more Cu 63's than 65's. This means that in a given sample of copper there will most likely be more 63's so when tested it clearly showed peaks just less than 64.