The Student Room Group

haloalkane to amine

In my notes it says that we need excess ammonia at roon temperature but need to use a high pressure in order to minimise further subsitution

If we want to minimise further substitution won't EXCESS ammonia encourage further substitution though?
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Original post by TheGreaterGood
In my notes it says that we need excess ammonia at roon temperature but need to use a high pressure in order to minimise further subsitution

If we want to minimise further substitution won't EXCESS ammonia encourage further substitution though?



If you used excess ammonia on a haloalkane you will first form a primary amine. Now if you had excess haloalkane at this point then your primary amine will react with the haloalkane to form a secondary amine. The secondary amine will then react with the haloalkane to form a tertiary amine etc...

If you use excess ammonia you form a primary amine with all the haloalkanes until it is all used up

Does that make sense?
Original post by Secret.
If you used excess ammonia on a haloalkane you will first form a primary amine. Now if you had excess haloalkane at this point then your primary amine will react with the haloalkane to form a secondary amine. The secondary amine will then react with the haloalkane to form a tertiary amine etc...

If you use excess ammonia you form a primary amine with all the haloalkanes until it is all used up

Does that make sense?


that was beautifully explained

yeah I understand now :biggrin:

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