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Ionic equations

Can someone help me on how to write equations? For example: Sodium carbonate solution with nitric acid and copper oxide with HCL. I know the balanced equations but where do I go next? How do I know which ions to keep in and which are spectators?

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Original post by Year11guy
Can someone help me on how to write equations? For example: Sodium carbonate solution with nitric acid and copper oxide with HCL. I know the balanced equations but where do I go next? How do I know which ions to keep in and which are spectators?


Moved to Chemistry section :smile:
Reply 2
Original post by Year11guy
Can someone help me on how to write equations? For example: Sodium carbonate solution with nitric acid and copper oxide with HCL. I know the balanced equations but where do I go next? How do I know which ions to keep in and which are spectators?


After having the balanced equation, split the ionic compounds into their ions. Then you removed the spectator ions and rewrite the ionic equation.
Reply 3
ok so:
CuO+2HCl--->CuCl2+H2O
Now split the ionic compounds into ions:
Cu+2 + O2- + 2HCl---> Cu2+ + 2Cl- + H2O
Is this right? How do I tell which the spectators are?
Original post by Year11guy
ok so:
CuO+2HCl--->CuCl2+H2O
Now split the ionic compounds into ions:
Cu+2 + O2- + 2HCl---> Cu2+ + 2Cl- + H2O
Is this right? How do I tell which the spectators are?


Looks good except for HCl. You have to split HCl into 2H+ and 2Cl-.
Spectator ions appear on both sides of the equation. So here you can see that 2Cl- is a spectator ion because it appears on both sides of the equation

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Reply 5
Original post by QuantumSuicide
Looks good except for HCl. You have split HCl into 2H+ and 2Cl-.
Spectator ions appear on both sides of the equation. So here you can see that 2Cl- is a spectator ion because it appears on both sides of the equation

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I thought HCl was covalent?
Original post by Year11guy
ok so:
CuO+2HCl--->CuCl2+H2O
Now split the ionic compounds into ions:
Cu+2 + O2- + 2HCl---> Cu2+ + 2Cl- + H2O
Is this right? How do I tell which the spectators are?

They'll appear on both sides of the reaction, like Cu2+ does.
Shouldn't HCl be split up into H+ and Cl-?
Reply 7
Original post by charlesn202
They'll appear on both sides of the reaction, like Cu2+ does.
Shouldn't HCl be split up into H+ and Cl-?

I didn't know it was ionic, I thought it was covalent.
Original post by Year11guy
I thought HCl was covalent?


Yep, HCl is covalent with a permanent dipole (electrons are attracted towards the Cl more strongly because Cl is more electronagtive). But i think in this case HCl is aqueous and aqueous species always separate into their ions.

This is what i've been taught. Maybe someone has a proper explanation.

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Original post by Year11guy
I didn't know it was ionic, I thought it was covalent.

HCl is covalent in gas form but when it's "dissolved" (I'm sure that's not the right word) in water the proton is released. That's one of the definitions of acidity anyways.
Reply 10
Original post by charlesn202
HCl is covalent in gas form but when it's "dissolved" (I'm sure that's not the right word) in water the proton is released. That's one of the definitions of acidity anyways.


Ah yes, how could I forget. It's the dissociation that makes acids acidic, am I right?
Original post by Year11guy
Ah yes, how could I forget. It's the dissociation that makes acids acidic, am I right?


Acids are proton donors. Here the HCl dissociates into H+ and Cl-

H2O acts as the base here:
H2O + H+ ---->H3O+

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Reply 12
Back to the question:

Cu+2 + O2- + 2H+ 2Cl- l---> Cu2+ + 2Cl- + H2O

The final equation after omitting Cu and Cl is:

O2- + 2H+ ------> H2O(l)
Original post by Year11guy
Back to the question:

Cu+2 + O2- + 2H+ 2Cl- l---> Cu2+ + 2Cl- + H2O

The final equation after omitting Cu and Cl is:

O2- + 2H+ ------> H2O(l)


Yeh fam. That's kool

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Reply 14
in my understanding only the dissolved ionic substances can be shown as separate ions - since copper oxide is insoluble in water it should not be shown as separate ions in the construction of your ionic equation so the e ionic equation is

CuO + 2H+ --> Cu2+ + H2O

only the Cl- ions are spectator ions
Reply 15
Original post by QuantumSuicide
Yeh fam. That's kool

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Ok, so if I try the next one by myself, the reaction of Sodium Carbonate with nitric acid.

Na+ + CO3(2-) + H+ + NO3- ------> Na+ + NO3- + H2O(l) + CO2.

Remove the spectator ions:


CO3(2-) + 2H+ ------> H2O(l) + CO2(g)

Is this correct, or are water and carbon dioxide ionic now too?
Original post by GDN
in my understanding only the dissolved ionic substances can be shown as separate ions - since copper oxide is insoluble in water it should not be shown as separate ions in the construction of your ionic equation so the e ionic equation is

CuO + 2H+ --> Cu2+ + H2O

only the Cl- ions are spectator ions


Im no expert but i know this isnt right. Dont ask me why tho lol

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Reply 17
Original post by QuantumSuicide
Im no expert but i know this isnt right. Dont ask me why tho lol

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Can you check the other one I just posted

Original post by GDN
in my understanding only the dissolved ionic substances can be shown as separate ions - since copper oxide is insoluble in water it should not be shown as separate ions in the construction of your ionic equation so the e ionic equation is

CuO + 2H+ --> Cu2+ + H2O

only the Cl- ions are spectator ions


The copper oxide is still involved in the reaction so it still separates into ions which may be why you're mistaken. I'm just going by what QuantumSuicide said as they said you're incorrect
Original post by Year11guy
Ok, so if I try the next one by myself, the reaction of Sodium Carbonate with nitric acid.

Na+ + CO3(2-) + H+ + NO3- ------> Na+ + NO3- + H2O(l) + CO2.

Remove the spectator ions:


CO3(2-) + 2H+ ------> H2O(l) + CO2(g)

Is this correct, or are water and carbon dioxide ionic now too?


Not quite fam. Sodium carbonate, Na2CO3, becomes 2Na+ and CO32-



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(edited 9 years ago)
Reply 19
Original post by QuantumSuicide
Not quite fam. Sodium carbonate, Na2CO3, becomes 2Na+ and CO32-



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I thought a nitrate ion has a 1- charge?

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