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ozone depletion equation

pls refer to the photo , i cant understand the notes on no8 . Why the net reaction is 2O3 →3O2?? after cancelling the ClO radical , i still cant get the equation right. pls help !!!
Reply 1
You could add O3 -> O2 + O. (O. appearing in step two of propagation).

I prefer ClO. + O3 -> Cl. + 2O2 in step 2.
Reply 2
Original post by Pigster
You could add O3 -> O2 + O. (O. appearing in step two of propagation).

I prefer ClO. + O3 -> Cl. + 2O2 in step 2.

why the author doesnt include the reaction equation O3 -> O2 + O. in the notes? this is making me confused.....
Reply 3
Original post by Pigster
You could add O3 -> O2 + O. (O. appearing in step two of propagation).

I prefer ClO. + O3 -> Cl. + 2O2 in step 2.

can you explain how is the equation ClO. + O3 -> Cl. + 2O2 in step 2. different form the propagation steps in the books?
Reply 4
I may be wrong (although Wikipedia agrees with my version of the equation), but it makes kinetic sense.

There is lots of O2 and some O3 in the high atmosphere. A small number of these are zapped by u.v. forming some O.

CFCs are zapped by u.v. forming a few Cl.

What is Cl. going to bump into? Most likely O2 or O3, forming a ClO. But what will that bump into? Most likely O2 or O3, how often will it bump into an O.?

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