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Moles

Can someone help me with Q10(d), I don't understand why we divide moles NaOH by 3, I though you would divide moles of the carboxylic acid by 3??? I always get confused with handling moles like these
http://filestore.aqa.org.uk/subjects/AQA-CHM6X-QP-JUN12.PDF
Reply 1
Original post by ps1265A
Can someone help me with Q10(d), I don't understand why we divide moles NaOH by 3, I though you would divide moles of the carboxylic acid by 3??? I always get confused with handling moles like these
http://filestore.aqa.org.uk/subjects/AQA-CHM6X-QP-JUN12.PDF


I'm not sure of the context of your statement highlighted in red.

But the calculations along the way should involve
moles of carboxylic acid = (moles of NaOH/3)
Reply 2
Original post by Metanoia
I'm not sure of the context of your statement highlighted in red.

But the calculations along the way should involve
moles of carboxylic acid = (moles of NaOH/3)


Could you explain why we divide NaOH by 3, and not the carboxylic acid?
Reply 3
I think I should edit my first post.

There are a maximum of 3 acidic groups COOH that could be created from the complete hydrolysis of each molecule of fat.

Working backwards

moles of NaOH = moles of COOH

moles of fat hydrolyzed = (moles of COOH)/3 or (moles of NaOH)/3
(edited 8 years ago)
Reply 4
Original post by Metanoia
I think I should edit my first post.

There are a maximum of 3 acidic groups COOH that could be created from the complete hydrolysis of each molecule of fat.

Working backwards

moles of NaOH = moles of COOH

moles of fat hydrolyzed = (moles of COOH)/3 or (moles of NaOH)/3


I did do COOH/3 but I keep getting a different answer


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Reply 5
Try posting your answers here.
Reply 6
Original post by Metanoia
Try posting your answers here.


I understand it now!

I have one ore question regarding moles... Q3... http://www.a-levelchemistry.co.uk/AQA%20A2%20Chemistry/Unit%206/ISA%20(EMPA)/AQA-CHM6X-W-SQP-07.pdf

I understand the concept gmol-1 x moldm-3 = gdm-3

But what data do I use in the introduction?
Reply 7
You know how many mol of Y there are in the titre.

You know that you used 1/10th of the standard solution you made up, so you know how many mol there were in the 250 cm3 standard solution.

Since you know that there is 1.419 g of carboxylic acid and you know how many mol that is, it is a simple calculation to work out its Mr.
Reply 8
Original post by Pigster
You know how many mol of Y there are in the titre.

You know that you used 1/10th of the standard solution you made up, so you know how many mol there were in the 250 cm3 standard solution.

Since you know that there is 1.419 g of carboxylic acid and you know how many mol that is, it is a simple calculation to work out its Mr.


But we're working out concentration???
Reply 9
Q1 - you work out the ave. titre of alkali.

From that you can work out how many mol. of NaOH.

Since all the carboxylic acids are monobasic acids i.e. 1 mol of acid releases 1 mol of H+.

Therefore the amount of acid is equal to the amount of alkali.

Which is in 25 cm3... calc me do.

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