Please someone help! When measuring the enthalpy change of combustions of different alcohols, why do we need to increase the temperature of the water by around 15-25 degrees?? Why 15 degrees? Why not 5? Why 25 degrees? Why not higher?
you need a decent temperature rise to minimise percentage errors. If the error in each thermometer reading is 0.25ºC then for a temperature rise of 5º the percentage error is 0.5/5 x 100 = 10%. This is clearly too great.
If the temperature rise is too large, however, you are starting to introduce problems of cooling due to CC&R and also evaporation of the water carrying off energy and changing the mass.