m/z = molecular mass; it's the mass over charge(which is always +1 unless you have a +2 spectrum graph).
the one furthest to the right is 9 times out of 10 the parent ion (ie the non-fragmented ion). The only time it isn't is if there are isotopes present.
Assuming the 208 peak is the furthest right, the species responsible for that would just be the parent ion which should/could be stated in the question.