The Student Room Group

Why is my working out wrong?!

The question is, the complete combustion of a hydrocarbon produced 0.352 grams of carbon dioxide and 0.108 grams of water. What is the empirical formula of the hydrocarbon?!

So what I did was,
CO2= 0.352/44= 0.008 mol

H2O= 0.108/18 = 0.006 mol

So I multiplied a 1000 to each mole so CO2= 8 and H2O= 6

So carbon=8 and hydrogen= 6x2=12

C8H12

But the answer is C2H3 :s-smilie: Whys that?
Hi,
Start with the equation
CxHy + O2 = CO2 + H20 (x and y variables)

The only source of C and H is from the CxHy

The amount of C in the CO2 = 0.352 X 12/44 (Mw C/ Mw CO2) = 0.0960g

Same for H in water = 0.108 X 2/18 (Note: 2 atoms of H) = 0.0120g

So moles of C present = 0.096/12 = 0.00800g Moles H =0.012/1 = 0.012

Empirical formula is the ratio of C:h: = 0.008:0.012 = 1:1.5 =2:3 So the empirical formula is C2H3 :smile: (Hopefully that is the right way of working the equation out, Good Luck :biggrin:)

TornadoLord125
Empirical formula is the simplest ratio. You most likely have the molecular formula.

C2H3 is the simplest Ration of C8H12.

You need to do what the post above says:tongue:
The carbon to carbon dioxide molecules ratio is 1:1 (because there Is 1 carbon atoms in each carbon dioxide molecule). This means that there are 0.008 moles of carbon atoms (as there are the same amount of carbon atoms as there are carbon dioxide molecules).

The hydrogen to water molecules ratio is 2:1 (because there are 2 hydrogen atoms in each molecules). This means that there are 0.006 x 2 = 0.012 moles of hydrogen atoms (as there are twice the amount of hydrogen atoms as water molecules).

The number of carbon and hydrogen atoms stay the same during the reaction so there are 0.008 moles of carbon and 0.012 moles of hydrogen in the hydrocarbon. This means that the ratio of carbon to hydrogen in a hydrocarbon molecule is 0.008:0.012 . This ratio is whole number ratio is 2:3, so the empirical formula is C2H3

Let me know if you need anymore explanation :smile:
Reply 4
Original post by TornadoLord125
Hi,
Start with the equation
CxHy + O2 = CO2 + H20 (x and y variables)

The only source of C and H is from the CxHy

The amount of C in the CO2 = 0.352 X 12/44 (Mw C/ Mw CO2) = 0.0960g

Same for H in water = 0.108 X 2/18 (Note: 2 atoms of H) = 0.0120g

So moles of C present = 0.096/12 = 0.00800g Moles H =0.012/1 = 0.012

Empirical formula is the ratio of C:h: = 0.008:0.012 = 1:1.5 =2:3 So the empirical formula is C2H3 :smile: (Hopefully that is the right way of working the equation out, Good Luck :biggrin:)

TornadoLord125


Original post by The Wavefunction
Empirical formula is the simplest ratio. You most likely have the molecular formula.

C2H3 is the simplest Ration of C8H12.

You need to do what the post above says:tongue:


Original post by fullmetal heart
The carbon to carbon dioxide molecules ratio is 1:1 (because there Is 1 carbon atoms in each carbon dioxide molecule). This means that there are 0.008 moles of carbon atoms (as there are the same amount of carbon atoms as there are carbon dioxide molecules).

The hydrogen to water molecules ratio is 2:1 (because there are 2 hydrogen atoms in each molecules). This means that there are 0.006 x 2 = 0.012 moles of hydrogen atoms (as there are twice the amount of hydrogen atoms as water molecules).

The number of carbon and hydrogen atoms stay the same during the reaction so there are 0.008 moles of carbon and 0.012 moles of hydrogen in the hydrocarbon. This means that the ratio of carbon to hydrogen in a hydrocarbon molecule is 0.008:0.012 . This ratio is whole number ratio is 2:3, so the empirical formula is C2H3

Let me know if you need anymore explanation :smile:


Great!! Thannx!:biggrin:

Quick Reply

Latest