The reaction should be dealt with as two separate half equations, one showing the oxidation and the other the reduction.
Then you balance electrons.
Then you add together.
Then you cancel out common terms.
You know the oxidation states of the iron, so let's start there:
FeO
42- + 8H
+ --> Fe
3+ + 4H
2O
now balance electronically
FeO
42- + 8H
+ + 3e --> Fe
3+ + 4H
2O
Now the other half equation involves formation of oxygen. The easiest way to do this is using water (it's in aqueous solution):
2H
2O --> 4H
+ + O
2 + 4e
Now equalise the electrons in the two half equations:
4FeO
42- + 32H
+ + 12e --> 4Fe
3+ + 16H
2O
6H
2O --> 12H
+ + 3O
2 + 12e
------------------------------------------------------------------------------ add together
4FeO
42- + 32H
+ + 6H
2O --> 4Fe
3+ + 16H
2O + 12H
+ + 3O
2Now cancel down common terms
4FeO
42- + 20H
+ --> 4Fe
3+ + 10H
2O + 3O
2Do a checksum with the charges
LHS = 12+
RHS = 12+