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Old 02-01-2008: 2nd January 2008 16:45 #1 
krisstassen krisstassen is offline
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Default Reaction of phenol with ethanoic acid!!
 
It is not in any of my revision guides..came up in the 2007 jan ocr salters paper..

I have seen the answer....basically an ester forms..but i dunno how or why...what if something similar comes up 2 weeks time!!

Major help required..thanks guys
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Old 02-01-2008: 2nd January 2008 17:22 #2 
melcarac melcarac is offline
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Default Re: Reaction of phenol with ethanoic acid!!
 
the reaction is not very efficient, as it will be really slow. so carboxylic acid derivatives like chloride or anhydride are used instead, because they are more reactive. anyway phenyl ethanoate is formed.
Old 02-01-2008: 2nd January 2008 17:29 #3 
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Default Re: Reaction of phenol with ethanoic acid!!
 
ah i see..........and hcl is the byproduct?
Old 02-01-2008: 2nd January 2008 17:53 #4 
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Default Re: Reaction of phenol with ethanoic acid!!
 
yes, when an acyl chloride is used
Old 02-01-2008: 2nd January 2008 22:47 #5 
thelostchild thelostchild is offline Male
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Default Re: Reaction of phenol with ethanoic acid!!
 
waters formed, just like any other esterification reaction with alcohol/carboxilic acid
 
Old 03-01-2008: 3rd January 2008 15:26 #6 
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Default Re: Reaction of phenol with ethanoic acid!!
 
Originally Posted by thelostchild
waters formed, just like any other esterification reaction with alcohol/carboxilic acid

Water forms only when you use an acid.
When the reaction is between phenol and acyl chloride (e.g. ethanoyl chloride) phenyl ethanoate and HCl are formed. If you use ethanoic anhydride, the products are phenyl ethanoate and ethanoic acid.
Old 03-01-2008: 3rd January 2008 16:20 #7 
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Default Re: Reaction of phenol with ethanoic acid!!
 
Originally Posted by melcarac
Water forms only when you use an acid.
When the reaction is between phenol and acyl chloride (e.g. ethanoyl chloride) phenyl ethanoate and HCl are formed. If you use ethanoic anhydride, the products are phenyl ethanoate and ethanoic acid.
I know that, I just read the thread title "Reaction of phenol with ethanoic acid!!" and just skimmed the rest of the thread, my bad
 
 
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