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RSS  Chemistry discussion, revision and homework help.
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Old 13-05-2008: 13th May 2008 19:43 #1 
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Default Dipoles
 
Why is C-Cl dipole more polar than C-Br? Is that an error with my revision guide? Because as i see it....Bromine is the larger atom, more electrons etc so surely it would be more electronegative creating a stronger dipole? Anyway any help would be greatly appreciated! Cheers
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Old 13-05-2008: 13th May 2008 20:03 #2 
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Default Re: Dipoles
 
Electronegativity is the ability to attract electrons towards the element (essentially). Therefore bromine will be less electronegative than chlorine as it has more electrons spread out which shield the +vely charged nucleus from attracting other electrons.
 
Old 13-05-2008: 13th May 2008 20:06 #3 
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Default Re: Dipoles
 
If you look at the electronegativity table, itl show u that there is more of a difference in the values of C and CL than between C and Br. x x
 
Old 13-05-2008: 13th May 2008 21:31 #4 
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Default Re: Dipoles
 
Yes thats right if you look its going across and up that increases the electronegativity
N O F Cl Br
Old 14-05-2008: 14th May 2008 16:27 #5 
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Default Re: Dipoles
 
Everyone's answers are correct; the bond is weaker, as there is electron shielding. You are probaly thinkning of Van der Waals/London forces. These will be stronger in the lower elements, as they have more electrons to form induced/instantanious bonds with.
Old 15-05-2008: 15th May 2008 17:04 #6 
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Default Re: Dipoles
 
F.o.n.cl.br.i

They are the most electroneg elements in order, also when Flourine bonds to something the bond produced is ionic due to the high electronegitivity and the electrons are attracted over the the F producing an ionic bond.
 
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