Perhaps one issue noone seems to have addressed is that without the cladding fibre can not be handled. Any point of the fibre which is in contact with anything absorbative of light would simply bleed off the light at the point it made contact with the fibre.
The fibre would have to be free standing and with the length of several kilometers that is a complete utter impossibility.
You could also not pack the fibres as they do so often together as any point where two fibres touched would leak into each other.
You should also know that Hasan is right. The highest quality fibres have the smallest possible critical angle, these are called single mode fibres, (the higher angles take up the higher spatial modes).