The Student Room Group

Addition of hydrogen halids to ethem

why is the rate of addition is in the order of their strength as acids?
HCl>HBr>HI
and why H+ ion adds first to the alkene
Reply 1
Original post by reb0xx
why is the rate of addition is in the order of their strength as acids?
HCl>HBr>HI
and why H+ ion adds first to the alkene


I don't think your order of acid strength is correct
Reply 2
Original post by chembob
I don't think your order of acid strength is correct


well then correct it for me and answer the question, please.
Reply 3
Original post by reb0xx
well then correct it for me and answer the question, please.


The order of acid strength goes as follows

HI > HBr > HCl

As an increasing size of anion --> poorer orbital overlap --> weaker bonding --> more likely to dissociate

Hence for HI you have greater concentrations of H+ and X- as compared to HBr or HCl

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