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Edexcel - Chemistry Unit 2 - 4 June 2013

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whats the shape and bond angles of: C2H6, C2H4, CH3OH AND CH3Cl thanks
Reply 741
Original post by Jayqwe
What about Fluorine?


Fluorine is an exception always. "The atom is so small that the repulsion between the in-coming electron and the seven electrons in the second shell reduces the energy liberated by the attraction between the incoming electron and the nucleus"

That's what george facer says, but I didn't quite understand it myself (if you do then I'd be grateful if you could explain it :smile: ). However I would no worry about this and stick with Cl, Br & I. Fluorine as a reducing or oxidizing agent is not mentioned in any other book & in past papers.
Reply 742
Original post by SophieL1996
whats the shape and bond angles of: C2H6, C2H4, CH3OH AND CH3Cl thanks


C2H6 - tetrahedral 109.5
C2H4 - trigonal planar 120
(though to be fair it's 118,121,121.. but I think they'll accept 120 :tongue: )
CH3OH - tetrahedral 109.5, bent 104.5
CH3Cl - tetrahedral 109.5
Original post by posthumus
Fluorine is an exception always. "The atom is so small that the repulsion between the in-coming electron and the seven electrons in the second shell reduces the energy liberated by the attraction between the incoming electron and the nucleus"

That's what george facer says, but I didn't quite understand it myself (if you do then I'd be grateful if you could explain it :smile: ). However I would no worry about this and stick with Cl, Br & I. Fluorine as a reducing or oxidizing agent is not mentioned in any other book & in past papers.


You mean Chlorine is the most powerful oxidizing agent of the halogens?
But all of Google says that fluorine can oxidize even chlorine and water?
:confused:
Reply 744
Original post by StUdEnTIGCSE
You mean Chlorine is the most powerful oxidizing agent of the halogens?
But all of Google says that fluorine can oxidize even chlorine and water?
:confused:


Well it's left out of book for a reason I guess :tongue: I've seen in previous papers that Chlorine is accepted to be the most powerful oxidizing agent. So I would honestly just stick with Chlorine.
Original post by posthumus
C2H6 - tetrahedral 109.5
C2H4 - trigonal planar 120
(though to be fair it's 118,121,121.. but I think they'll accept 120 :tongue: )
CH3OH - tetrahedral 109.5, bent 104.5
CH3Cl - tetrahedral 109.5

thank you :smile: why is c2h2 trigonal planar though?
are we all ready to get raped by edexcel tomorrow hahahahahah

anywayz every just listen to this

https://www.youtube.com/watch?v=HgzGwKwLmgM
Reply 747
Original post by SophieL1996
thank you :smile: why is c2h2 trigonal planar though?


C2H4 is trigonal planar because if you cut it in half it has CH2 and a double bond which resembles the shape of a triangle and if you do 360/3 you get 120
Reply 748
Original post by SophieL1996
thank you :smile: why is c2h2 trigonal planar though?


There's 3 bonds around the carbon atom

2 single bonds (C-H) & 1 double bond (C=C) & there's no lone pairs :smile:
What do we need to know about fullerenes ?
(edited 10 years ago)
Can someone confirm this...

When we are titrating K2MnO4 K_2MnO_4 it is kept in the burette.
And in iodometric tritrations iodine is in the conical flask and at the end point the starch complex turns from blueblack to colourless?
Original post by StUdEnTIGCSE
Can someone confirm this...

When we are titrating K2MnO4 K_2MnO_4 it is kept in the burette.
And in iodometric tritrations iodine is in the conical flask and at the end point the starch complex turns from blueblack to colourless?


Yeah, that's right :smile:
Reply 752
Am I right to believe the mark scheme makes no sense over here ? & is not answering the question

CHM2WTFMS.png

Could someone also explain to me how to do this question :

When chlorine is added to a solution containing bromide or iodide ions, a colour
change occurs. What solvent would you add to the mixture to confirm the
identity of the halogen produced?


Thanks in advance ! :smile:
Reply 753
Original post by TheUndercoverPanda
What do we need to know about fullerenes ?


Everything :smile:
Just a few uses like they can cage drugs, etc...
And their electrical conductivity and general properties...


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Reply 754
Original post by posthumus
Am I right to believe the mark scheme makes no sense over here ? & is not answering the question

CHM2WTFMS.png

Could someone also explain to me how to do this question :

When chlorine is added to a solution containing bromide or iodide ions, a colour
change occurs. What solvent would you add to the mixture to confirm the
identity of the halogen produced?


Thanks in advance ! :smile:


Add a hydrocarbon solvent like hexane and it turns purple


Posted from the TSR iPad app
what is the name of (ch3)2 chch3oh ? what does it look like?
tdoes anyone know what back titrations are? do we need to know about them, my teacher says yes but ive never come across this term before..
Original post by SophieL1996
what is the name of (ch3)2 chch3oh ? what does it look like?




Posted from TSR Mobile

Surely you must be able to name this?
(edited 10 years ago)
Reply 758
Can anyone explain how this question is done please... Couldn't find stuff about it in the textbook or CGP revision guide...
It's from the January 2012 paper btw
ImageUploadedByStudent Room1370261832.240696.jpg


Posted from the TSR iPad app

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