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OCR Gateway Chemistry C4C5C6 - 13/06/13

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Reply 400
Original post by Daniel97g
Can anyone explain how an ion-exchange resin works?


yeah okay so basically it has sodium ions on its surface and when calcium ions from hard water flow past they are attracted to the surface and stick to it, knocking the sodium ions into the water. The water is soft because the calcium ions have been removed and the sodium ions do not effect the soap. The calcium ions can then be removed by concentrated salt solution as it knocks them off and replaces them with fresh sodium ions.

sorry if that made no sense xx
Original post by Knowing
You're welcome ^^



(If all the sodium ions have been replaced, you just flush the column with NaCl solution again, clearing away the Ca/Mg ions, and regenerating it with new sodium ions)


Understood, how do you what atoms are more reactive? (for example, in this case Mg and Ca are more so than Na?) Thank you!
Reply 402
Original post by Daniel97g
Understood, how do you what atoms are more reactive? (for example, in this case Mg and Ca are more so than Na?) Thank you!


Mg and Ca are both ions with a charge of +2. This is double the charge of Na, which has a charge of +1, so Mg/Ca attract twice as much as Na.
Original post by Knowing
Mg and Ca are both ions with a charge of +2. This is double the charge of Na, which has a charge of +1, so Mg/Ca attract twice as much as Na.



Oh right, compare fermentation and hydration for producing ethanol?
What are the total UMS marks that the whole gcse is out of? And how many would you need total for a A* and an A? Thanks!
Original post by Knowing
You're welcome ^^


Basically you have an "ion-exchange column", which is packed with small beads. When you flush sodium chloride solution through it (salt water basically), the sodium ions get attached to the ion-exchange resin/beads. When hard water (water with calcium and magnesium ions in) passes through the ion-exchange column, the calcium/magnesium ions in the water are swapped with the sodium ions in the column, because calcium is more attractive. Therefore, the sodium ions replace the calcium/magnesium ions in the hard water, softening it.

(If all the sodium ions have been replaced, you just flush the column with NaCl solution again, clearing away the Ca/Mg ions, and regenerating it with new sodium ions)


Original post by ChloBrown98
Ions can be formed when electorns are lost or gained if this helps :smile: and I have no clue about what the 'resin' part is. Sorry :frown:


Original post by izzzyyay
yeah okay so basically it has sodium ions on its surface and when calcium ions from hard water flow past they are attracted to the surface and stick to it, knocking the sodium ions into the water. The water is soft because the calcium ions have been removed and the sodium ions do not effect the soap. The calcium ions can then be removed by concentrated salt solution as it knocks them off and replaces them with fresh sodium ions.

sorry if that made no sense xx


You guys have cleared c4/5/6 up for me! Thanks :smile: I'm unprepared -.-



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Reply 406
Any one prepared any 6mark answers for c4c5andc6?

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Reply 407
Original post by Daniel97g
Oh right, compare fermentation and hydration for producing ethanol?


Fermentation:

Renewable;
Low temperature, medium pressure;
Low percentage yield;
Low atom economy;
Batch process.

Hydration:

Non-renewable (ethene from crude oil);
High temperature + pressure;
High percentage yield;
High atom economy;
Continuous process.
Reply 408
Original post by Knowing
Fermentation:

Renewable;
Low temperature, medium pressure;
Low percentage yield;
Low atom economy;
Batch process.

Hydration:

Non-renewable (ethene from crude oil);
High temperature + pressure;
High percentage yield;
High atom economy;
Continuous process.


So hydration wud be better right? :lolwut:

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Reply 409
Original post by AR-13
So hydration wud be better right? :lolwut:

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That's for you to choose :tongue:

If there's a 6 marker on it, it'll probably ask you which you think is better and why, so just list the differences and use your own judgement - you can say either could be better if you justify it.
Original post by Knowing
Fermentation:

Renewable;
Low temperature, medium pressure;
Low percentage yield;
Low atom economy;
Batch process.

Hydration:

Non-renewable (ethene from crude oil);
High temperature + pressure;
High percentage yield;
High atom economy;
Continuous process.


I think fermentation has a high yield and low atom economy whilst hydration has a low yield and high atom economy. The hydration reaction is reversible which causes the low yield whilst fermentation is not reversible, which results in it having a higher yield...
This is what my revision guide is telling me :redface:


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Really hoping most people are unprepared as it is one of the later exams so that the grade boundaries will be lower... :frown:
Original post by Puffin111
Really hoping most people are unprepared as it is one of the later exams so that the grade boundaries will be lower... :frown:


Let's hope so, I am literally just cramming everything from all the units, starting C6 now. :eek:
Reply 413
Original post by BP_Tranquility
I think fermentation has a high yield and low atom economy whilst hydration has a low yield and high atom economy. The hydration reaction is reversible which causes the low yield whilst fermentation is not reversible, which results in it having a higher yield...
This is what my revision guide is telling me :redface:


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If it's worked, I've attached what my textbook says.
Reply 414
It would make sense that a reversible reaction would be 100% yield, since the unreacted reactants can be re-used again.

Also, you would lose a lot of yield during fermentation, as you have to evaporate and filter and what not to remove the ethanol from the yeast.
(edited 10 years ago)
Original post by Knowing
It would make sense that a reversible reaction would be 100% yield, since the unreacted reactants can be re-used again.

Also, you would lose a lot of yield during fermentation, as you have to evaporate and filter and what not to remove the ethanol from the yeast.


True, but surely a reversible reaction also allows an equilibrium to be formed? Because hydration requires a large amount of energy which would increase the chances of the backward reaction speeding up, breaking down the product and reducing yield... :smile:


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Reply 416
Dyou hav to memorise the molecular formulas of alcohol, or wud they giv u?

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Original post by AR-13
Dyou hav to memorise the molecular formulas of alcohol, or wud they giv u?

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:dontknow:

Remember it's:

Like alkanes but OH on the end :smile:

CH3OH
C2H5OH
Reply 418
Original post by BP_Tranquility
True, but surely a reversible reaction also allows an equilibrium to be formed? Because hydration requires a large amount of energy which would increase the chances of the backward reaction speeding up, breaking down the product and reducing yield... :smile:


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Just realised: it's not a reversible reaction.ImageUploadedByStudent Room1371106319.709332.jpg


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Reply 419

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