Significant figures is about the information you have, and the uncertainty.
There is no information about the size of 0.0000304572 before the three, because it's just a series of zeros. It can't tell you when it stops, until you see a non-zero number.
Once you have your first three (or any other non-zero number for that matter), you know the rough size. That's where your significant figures start - your first non-zero number.
The number of significant figures is just counting the number of figures from the first non-zero. If you have three significant figures, it would be 0.0000305 as the fourth significant figure is 5 or greater (so it rounds up)
The reason why you're asked to do this is because in a lot of calculations, you get a massive string of numbers in your calculations but your uncertainty is much bigger so you have to truance your numbers a bit.
The same is true if you're measuring something with a ruler, you can't measure more precisely than to the nearest 0.1cm unless you use a ruler with smaller graduations but your calculations might spit up something like 5.6666666666666cm if you divide by three.