In GCSE we learnt about how change in concentration and pressure will change the position of equilibrium but how come it doesn't change Kc since Kc can measure the position of equilibrium
In GCSE we learnt about how change in concentration and pressure will change the position of equilibrium but how come it doesn't change Kc since Kc can measure the position of equilibrium
Because Kc is a constant. It shows that when you disturb a condition in a system that is at equilibrium, the system will oppose that change so that equilibrium can be established again. So for example if you increased pressure, the system will favour the side of the reaction where there are fewer gas molecules, so as to reduce the pressure again. This maintains equilibrium, which is why Kc is constant.
wait so let say A+B → 3C. A B and C are all gases initially in GCSE we say if pressure increase then the position of equilibrium shifts to the left since there are less moles. Now in A level, do we say that position of equilibrium shifts to the left to restore the value of Kc to reach equilibrium once again, right? Surely that would mean that at the instant of increasing the pressure, the position of equilibrium lies well on the right so that it needs to shift back to left to restore equilibrium?
Also since Kc is constant why would change in temperature change Kc?
Because Kc is a constant. It shows that when you disturb a condition in a system that is at equilibrium, the system will oppose that change so that equilibrium can be established again. So for example if you increased pressure, the system will favour the side of the reaction where there are fewer gas molecules, so as to reduce the pressure again. This maintains equilibrium, which is why Kc is constant.
Only temperature affects Kc. If you disturb the equilibrium, it will oppose the disturbance and shift to the side where there is less disturbance. This effectively means that the concentration of reactants and products remains the same so Kc does not change.
the reason why we say kc isnt effected by pressure is because a pressure has to be maintained in order to disrupt the eq so, in a system if pressure is changed the eq is temporarily not = to kc
In GCSE we learnt about how change in concentration and pressure will change the position of equilibrium but how come it doesn't change Kc since Kc can measure the position of equilibrium
the reason why we say kc isnt effected by temp is because a temperature has to be maintained in order to disrupt the eq so, in a system if temp is changed the eq is temporarily not = to kc
Wait so to summarise. so when pressure is increased the equilibrium is distorted. kc stays the same Therefore the position of equilibrium needs to shift to restore Kc? (e.g left) Does that therefore imply that at the instant that the pressure is changed (when equilibrium is distorted) the position lies on the right so that it needed to shift to left to restore Kc?
the reason why we say kc isnt effected by pressure is because a pressure has to be maintained in order to disrupt the eq so, in a system if pressure is changed the eq is temporarily not = to kc
Wait so to summarise. so when pressure is increased the equilibrium is distorted. kc stays the same Therefore the position of equilibrium needs to shift to restore Kc? (e.g left) Does that therefore imply that at the instant that the pressure is changed (when equilibrium is distorted) the position lies on the right so that it needed to shift to left to restore Kc?
kc is a fixed constant, therefore as soon as the preassure is no longer maintained, the system will revert back to the initial eq because the pressure is nolonger being exerted on the system, therefore kc doesnt change is just that its 'distorted' as you put it
kc is a fixed constant, therefore as soon as the preassure is no longer maintained, the system will revert back to the initial eq because the pressure is nolonger being exerted on the system, therefore kc doesnt change is just that its 'distorted' as you put it
Even then, why does temperature affect Kc since temperature surely disrupts the equilibrium too?
this ones quite simple. for pressures we use kp not kc as kp works for gaseous systems. we can change the temp and therefore KE of both gases AND liquids. however you cannnot change the pressure of a liquid! therefore change in pressure is said to have no real effect pm me if this still doesnt make sense
this ones quite simple. for pressures we use kp not kc as kp works for gaseous systems. we can change the temp and therefore KE of both gases AND liquids. however you cannnot change the pressure of a liquid! therefore change in pressure is said to have no real effect pm me if this still doesnt make sense