Hi. I'll start by giving some formulae/concepts you need to solve the questions to see if you can work it out from there. If not then I'll give further help
Q1) 250ml = 0.25l (I know this is a bit obvious but could be easy to forget to convert) mol = concentration * volume mass = mol * Mr
From the above information you can figure out how many moles you need of the zinc nitrate to get that concentration for the stated volume, and therefore the mass.
Q2) 50ml = 0.05l mol = concentration * volume
For this one I could be wrong but I think it ends up being simpler than it sounds. Once you find the moles of HCl you have in 0.05L you only need to do a quick subtraction to find the answer if you think about what all of the units mean. I appreciate this help is a bit vague but if you can figure it out for yourself I don't want to give too much away and take away any satisfaction!