Okay then, I presume you know how to find an angle between two lines which intersect in 3D, or more specifically, how to find the angle between any two vectors. Look at the diagram below.
Suppose we have some plane
Π and a line
ℓ going through it. The angle between these is marked as
θ. One approch to determine it, is to firstly determine what
α is, which is presicely the angle between the normal to the plane,
n, and the line
ℓ. If you can do that, then it's a simple matter of realising that
α+θ=90, therefore our angle is given by
θ=90−α.
In your question, you can think of
ℓ as being your vector
a, and the plane
Π being the xy-plane
z=0. Have a go.
No fully worked solutions will be provided to you, it's not the kind of site where others do your work for you. Post your working out if you get stuck.