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    To my knowledge straightening shampoos don't actually straighten your hair, but instead are geared towards reducing frizz and making already straight hair look properly straight.

    This makes complete sense when you consider that hair patterns determined by the physical properties of the hair fibres, and merely shampooing them can't change that. You need something which physically traumatises those fibres, such as a straightening iron or a chemical relaxer.
 
 
 
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