react with Tollen's reagent [Ag(NH3)2] . Methanoic acid will reduce it to Ag (s) which forms as a silver mirror. Ethanoic acid will not reduce Tollen's reagent. This occurs as Methanoic acid acts as both and aldehyde and an acid, so t is able to act as a reducing agent. Ethanoic cannot act as a reducing agent as it does not posses an aldehyde group.