1)Vgrav=-GM/R
On Surface: -(6.67x10^-11*6x10^24)/6.4x10^6=-6.25x10^7
In orbit: -(6.67x10^-11*6x10^24)/4.23x10^7=-9.46x10^6
-9.46x10^6-(-6.25x10^7)=5.3x10^7
2)Gravitational potential energy at infinity is 0.
0-6.25x10^7=-6.35x10^7
EDIT:I worked out what i did wrong. Multiply the values by the mass of the other object. -(GMm)/r