I appreciate that at A-level standard, electron standing waves around nuclei aren't explored in great depth, but I'm struggling with the idea of the potential energy around a nucleus forming 'walls' which electrons form standing waves between.
Decreasing an electron's wavelength increases it's kinetic energy proportional to 1/(wavelength)2 , and getting closer to the nucleus of an atom makes the negative potential energy more negative, proportional to 1/radius. My study book states that 'if the kinetic energy is larger than the negative potential energy, the electron will escape the nucleus'.
Do the standing waves with longer wavelengths exist further from the nucleus? This would mean their potential energy would be less negative, and closer to their kinetic energy, but I was under the impression (from previous studying) that the electrons with the most kinetic energy were furthest from the nucleus, which explains why they were easiest to remove.
Surely if the electrons have more kinetic energy they exist further from the nucleus, because it takes an increase in energy to get from the nucleus to a point further away!
Sorry if I'm being dim, any answers or suggestions very welcome.
Thanks