You should probably be able to do it with the Polo battery, assuming it hasn't been replaced in the past with a smaller one than standard. In warm weather like this (pah) engines don't use the full capacity of the battery (reserved for cold starts down to ten-twenty degrees below). Your main issue will be the cheapy cables, they simply won't let enough current to start the Merc through. Borrow or buy some fat ones and you'll be set for life. My Grandad gave me a set you could start a jumbo jet with and nothing has yet phased them, and I've managed to start far larger vehicles than my old 1.4 petrol Golf with them.
Make sure you do one cable first, then the other. Don't connect both at one end and then both at the other, as you'll probably end up touching the jaws together and scaring yourself with the nice big resulting spark. Start the Polo and leave it running for five minutes, and then try starting the Merc. Get somebody to sit in the Polo and build the revs up until there's enough power to turn the Merc over, as alternators make exponentially more power, the more the engine's being revved.
If that really doesn't work, then they're fairly easy to bump-start. I've bump started cars on my own on flat ground before, so given a couple of mates you could bump start a van. Turn the key to the on position, stick it in second (maybe third, given the compression of a big diesel engine) and clutch down. Get it up to 5-10 mph and then dump the clutch. If you're on a hill leave the clutch and let the momentum of the van turn the engine over before giving it some throttle. If you're on the flat, as soon as the engine catches drop the clutch to the floor and give it some throttle. Should be enough to get it going.