Voltage = Power/Current Power = Energy/Time (Joules/second) Energy = Force * Distance Force = Mass * Acceleration (Newton's 2nd law)
=> SI base units of Force: kg m s-2 => SI base units of Energy: kg m2 s-2 => SI base units of Power: kg m2 s-3 => SI base units of Voltage: kg m2 s-3 A-1
Having said that, charge was defined to me as 'one coulomb is the charge that is transferred when one amp flows for one second'. So I guess you're right, Amperes are the 'first' unit and so the SI one. It just seems weird because usually things are not defined as a product of time and another thing. Like a metre isn't defined as the distance moved when something going 1m/s moves for 1 s. Or maybe it is
ahh that's interesting thanks. A second is defined as something to do with caesium is it not, so in that way it does look like the time-related thing is more fundamental.