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Yield calculation help

Hey, I recently did a yield calculation question which I was told was calculated wrong. It was for a reaction of copper acetate with glycine to form copper glycine. Can you tell me where I went wrong?

Cu(CH3COO)2H2O + 2H2NCH2COOH Cu(H2NCH2COO)2H2O + 2CH3COOH

Actual yield = 1.455g

Mass of copper (II) acetate = 1.598g

Moles of copper (II) acetate = 1.598/199.65 = 8.00 x 10-3 moles

Mass of glycine = 1.165 g

Moles of glycine = 1.165/75.07 = 0.0155 / 2 = 7.75 x 10^-3 moles (Limiting reagent)

Theoretical yield = 7.75 x 10^-3 x Mr Cu(gly)2H2O = 7.75 x 10^-3 X 229.66 = 1.78g

% yield = 65.45%
(edited 10 years ago)
Original post by Naami
Hey, I recently did a yield calculation question which I was told was calculated wrong. It was for a reaction of copper acetate with glycine to form copper glycine. Can you tell me where I went wrong?

Cu(CH3COO)2H2O + 2H2NCH2COOH Cu(H2NCH2COO)2H2O + 2CH3COOH

Actual yield = 1.455g

Mass of copper (II) acetate = 1.598g

Moles of copper (II) acetate = 1.598/199.65 = 8.00 x 10-3 moles

Mass of glycine = 1.165 g

Moles of glycine = 1.165/75.07 = 0.0155 / 2 = 7.75 x 10-3 moles (Limiting reagent)

Theoretical yield = 7.75 x 10-3 x Mr Cu(gly)2H2O = 7.75 x 10-3 X 229.66 = 1.78g

% yield = 65.45%


You didn't say how you calculated the percentage yield, it should be actual yield divided by the theoretical yield then multiply by 100 to make it a percentage.
Reply 2
Original post by Scorlibran
You didn't say how you calculated the percentage yield, it should be actual yield divided by the theoretical yield then multiply by 100 to make it a percentage.


Yeah that was a silly mistake on my part. My demonstrator however says it's my theoretical yield that is incorrect, and I don't really know where?
Original post by Naami
Yeah that was a silly mistake on my part. My demonstrator however says it's my theoretical yield that is incorrect, and I don't really know where?


I checked your calcs and it seems to be correct, are you sure your demonstrator didn't get it wrong?
Reply 4
Original post by Scorlibran
I checked your calcs and it seems to be correct, are you sure your demonstrator didn't get it wrong?


I'm starting to think he did which is really annoying as he's docked off 4/6 marks for it! :mad:
Reply 5
Why do you assume it is dihydrate? As far as I can tell it is either anhydrous, or monohydrate.

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