The Student Room Group

PH3, AsH3, SbH3 Intermolecular forces

My book keeps referring to how the group 5 hydrides have only VDW forces, with no permanent dipole-dipole interactions.

Surely this is incorrect; the lone pair on each of these molecules results in a trigonal pyramidal shape, and thus a polar molecule?

Hence the group 5 hydrides should have permanent dipole-dipole interactions?
Original post by Cruckshank
My book keeps referring to how the group 5 hydrides have only VDW forces, with no permanent dipole-dipole interactions.

Surely this is incorrect; the lone pair on each of these molecules results in a trigonal pyramidal shape, and thus a polar molecule?

Hence the group 5 hydrides should have permanent dipole-dipole interactions?


They do ...

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