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OCR A2 Chemistry Unit 5, F325 15th June 2015

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Ugh i got 4.3x on the magnesium buffer, don't think that's right, most stuff seem good tho, i only got max 3 marks on the last question, plus i did the last 3 marker in acid conditions. I think the paper was good for most of it tho. Got 8.4x104 for the rate question, 0 for the ph of hydrogen electrode. 56.7/57.6 summert for kc. Starting to see I've lost some easy marks unfortunately 😫 still think I've got a good chance of getting a high B though, if not a low
Reply 3981
Original post by Nikeshp79
It can't as it contains no protons to donate


Another stupid mark lost
Original post by ForgottenApple
Dunno lol
Most discriminating mark on paper imo -> Iodine as a solid lmao


haha! :smile:
Reply 3983
PLEASE DOES SOMEONE REMEMBER THE VALUES FOR THE DILUTION pH QUESTION??
Guys is there an unofficial mark scheme?
Original post by games211
did anyone get 8.3 for anything?


I got 8.3 recurrent for Kc but everyone else got 8.3 * 10^4
Did anyone put i2 in solid state when filling in equations for haber cycle?
did anybody put H+ ions for the last question involving Cr?
for the adding cobalt or copper to ammonia etc did we just have to put the complex ion examples???
Original post by ECrazyMeC
Did anyone put i2 as solid when filling in equation for haber cycle??


Yeah, I am pretty sure iodine's standard state is solid.
was CR +3 ON FIRST q?!!?
Reply 3991
would we only lose 1 or 2 marks for doing the equations in acidic conditions?
Original post by ECrazyMeC
Did anyone put i2 in solid state when filling in equations for haber cycle?


I did
>oxidation number (1)
>example of catalysis (1)
>bidentate definition (1)
>formula of the bidentate ligand (1)
>structure of the bidentate ligand and how it acts as a ligand (2)
>draw the optical isomers (1)
>reactions of Cu2+ ions (6)


>calculate Kc (6)
>what happens to pressure as equilibrium is approached (1)
>predict the sign and explain effect on yield (2)
>oxygen is now in excess, state and explain effect on Kc (3)

>calculate k (4)
>graphs for two temperatures (2)
>effect on k (1)
>graph for the first order relationship (2)

>acid definitions (1)
>pH of base (2)
>pH of solution (2)
>full equation (1)
>ionic equation (1)
>pH of buffer (1)
>adding NH3 and the effect on equilibrium (2)
>pH when Mg was added (4)

>predict the products when Fe2+ reacts with halogens (3)
>order of negativity (1)
>ph electrode question (1)
>question below this about equilibrium (2)
>conjugate acid-base pair question (1)
>why not use acidic conditions (1)

>born-haber cycle (4)
>lattice enthalpy definition (2)
>calculate lattice enthalpy (2)

>calculate entropy for hydrogen (2)
>calculate delta G and discuss feasibility (2)
>explain the significance of the temperature relating to feasibility (2)

>2 reactions (2)
>percentage purity (6)
>equations (last question) (3)

82 marks
Original post by tewas
Shall i make an unofficial? Send me asnswers and questions

Yes please!! but i cant remember any questions
Original post by tewas
would we only lose 1 or 2 marks for doing the equations in acidic conditions?


that's what i did, but apparently we are meant to use OH- instead of H+ ions
Original post by kaihiwatari
Ugh i got 4.3x on the magnesium buffer, don't think that's right, most stuff seem good tho, i only got max 3 marks on the last question, plus i did the last 3 marker in acid conditions. I think the paper was good for most of it tho. Got 8.4x104 for the rate question, 0 for the ph of hydrogen electrode. 56.7/57.6 summert for kc. Starting to see I've lost some easy marks unfortunately 😫 still think I've got a good chance of getting a high B though, if not a low


Other 2 yes.
Magnesium one is tricky
0.25 mol of Mg means 0.5 mol of acid will react
so [C2H5COO-]=1.5M
[C2H5COOH]=0.5M

pH=-log(1.35E-5) +log(1.5/0.5)
pH=5.35 right?
[QUOTE=justfly;57047281]was CR +3 ON FIRST q?!!?

+5
Original post by HennersPD
haha! :smile:


Was thinking that as I did it!
I was like they've deliberately shown iodine as a gas in every step!!!
Synoptic mark anywho
Original post by Hazza_
Yeah, I am pretty sure iodine's standard state is solid.


Yay!

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