d) That is the same as there being breakdowns in at most 2 blocks of 12 weeks.
The probability of there being at least one breakdown is 0.221. You want the sum of P(no breakdowns) + P(breakdowns in one block of 12 weeks only) + P(breakdowns in 2 blocks of 12 weeks only).
I'd use Bin(20, 0.221) and calculate it using nCr.
For the second bit:
Use a poisson distribution if it gives you an average rate of occurence, but binomial if you have to work out combinations of True/False occurences. Basically, if you know the probability of an outcome of a specific event, use binomial.