Just multiply (i) by two. The equation says that one mole of N2O4 gives two moles of NO2.
The second question:
Work out, for each species:
(i) initial amounts: 62.8, 146, 0
(ii) change: -x, -2x, +x
(iii) final amounts , 62.8-x, 146-2x, x
x = 26.2, so work out the rest.
The rest you should be able to do.