Platinum electrodes are used when:
1. it's a gas/aqueous ions half cell
eg H2(g)/H+(aq)
2. it's an aqueous ions half cell
eg Fe2+(aq)/Fe3+(aq)
What it is doing in the cell--- source or sink of electrodes
Why we choose platinum--- good conductivity, inert metal
I think that's what my notes say, anyways~
selkie