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A difficult half-life question! :/

If, during a first order reaction, the concentration fell to 12.5% of its original value in 24 minutes, what is the half life of the reaction?
It's not really that difficult.
Think about it - there is a 12.5% decrease in 24 minutes so how long will it take for it to have a 50% decrease.

12.5% = 24
50% = ?

You need to do 50/12.5 and with that answer multiply it to 24
Reply 2
Original post by Namita Gurung
It's not really that difficult.
Think about it - there is a 12.5% decrease in 24 minutes so how long will it take for it to have a 50% decrease.

12.5% = 24
50% = ?

You need to do 50/12.5 and with that answer multiply it to 24


I got 96 min but the answer in my book is 8 min?!
You first have to find out how many half lifes there is overall. So you can keep halving from 100 until you get to 12.5. 100 - 50 - 25 - 12.5 which equates to 3 half lifes because it has been halved 3 times. So now you know there are 3 half lifes in 24 minutes so to find the length of one you do 24/3 which = 8 minutes and therefore one half life is 8 minutes. Hope that helped! :smile:
(edited 7 years ago)
Reply 4
Original post by Samii123
You first have to find out how many half lifes there is overall. So you can keep halving from 100 until you get to 4. 100 - 50 - 25 - 12.5 which equates to 3 half lifes because it has been halved 3 times. So now you know there are 3 half lifes in 24 minutes so to find the length of one you do 24/3 which = 8 minutes and therefore one half life is 8 minutes. Hope that helped! :smile:


Oh i see, thank you!
Original post by Adorable98
Oh i see, thank you!


You're welcome :biggrin:
(edited 7 years ago)
Reply 6
Original post by Samii123
You're welcome :biggrin:


I've got one more question please.

If the initial concentration in a first order reaction [would it be any different if it was a zero or a second order reaction??:redface:] with a half life of 12 minutes was 0.400 moldm-3, what would the concentration be after 48 minutes?
Original post by Adorable98
I've got one more question please.

If the initial concentration in a first order reaction [would it be any different if it was a zero or a second order reaction??:redface:] with a half life of 12 minutes was 0.400 moldm-3, what would the concentration be after 48 minutes?


With a half life of 12 minutes, in 48 minutes there would be 4 half lifes that have occurred as 48/12 = 4. So then you must half the concentration a total of 4 times. 0.400 - 0.200 - 0.100 - 0.05 - 0.025. So your final answer is 0.025moldm^-3.
Also first order reactions are when the rate of reaction is directly proportional to the change in one reactant and therefore half life can be calculated accurately. In a second order reaction the rate depends on two substances and therefore half life cannot be calculated as accurately and it becomes a more complex calculation.
Reply 8
Original post by Samii123
With a half life of 12 minutes, in 48 minutes there would be 4 half lifes that have occurred as 48/12 = 4. So then you must half the concentration a total of 4 times. 0.400 - 0.200 - 0.100 - 0.05 - 0.025. So your final answer is 0.025moldm^-3.
Also first order reactions are when the rate of reaction is directly proportional to the change in one reactant and therefore half life can be calculated accurately. In a second order reaction the rate depends on two substances and therefore half life cannot be calculated as accurately and it becomes a more complex calculation.

I see thank you so much!
So do you think we'll only be asked half-life questions for 'a first order' at A2?
I'm doing Edexcel.
Original post by Adorable98
I see thank you so much!
So do you think we'll only be asked half-life questions for 'a first order' at A2?
I'm doing Edexcel.


I'm not sure, you could have a look at the specification however.

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