Ok, the best way to think about it is to draw an imaginary right-angled triangle between the observer, the plane and the ground. I'll assume you mean theta is the angle made as the observer looks up at the plane from the ground. This means that the angle with the vertical is π/2-π/3 = π/6
..Plane ------X
.......\.......|_|
........\.........|
.........\........|
..........\.......|3km
...........\.π/6.|
............\.....|
.............\....|
______Observer
Now we can work out the distance that the plane is from the point directly above the observer, that I've called X. This is 3tan(π/6) = √3 km
Now here's the clever bit. You could try working out the distance the plane travels in a second but then you'll have to work out the tan of some horrible angle. What you can instead do is notice that if the plane covers 1/60 rad per second, then in 10π seconds it would have covered 10π/60 = π/6 rad.
Thus, the speed of the plane is √3 ÷ 10π = 0.055... km/sec
= 198 km/h (to 3sf)
Check that one time