First, the idea of potential difference is the work done per unit charge.
So the electrons from V1 has potential=10V, electrons from V2 has potential=12V, you can't add those two together.
potential at the junction below R3 must always be 0 V because you assume the wire has resistance = 0
the potential at the junction between R1 and R2 must be 10 V since no work is done on R1
Therefore, pd across R3 is 10V when R1=0, and pd across R2=12-10=2V
Once you increase the resistance of R1, some of the energy is dissipated on R1, so the potential at the junction between R1 and R2 decreases.
Then follow the same idea above, you can answer part 03.4