The Student Room Group

Reply 1

Umm you can determine the overall rate of the reaction by looking at the initial rate? , its the rate determining step?

Reply 2

As the reaction proceeds the concentrations of the reagents are not known. However, at the start of the reaction the initial concentration of the reagents IS known.

Any orders that are calculated from average rates may not take into accound such factors as autocatalysis or any mechanistic change due to concentration effects.

Initial rates allow more reliable information to be determined regarding orders, activation energies and possible mechanisms (which is the ultimate aim of reaction kinetics)

Reply 3

Cheers that's really useful :biggrin: +rep