Er, curare is a molecule which has a similar shape to acetylcholine and competes against it for receptor proteins on the post-synaptic membrane. In contrast however, it does not cause a conformational change which opens sodium channels on the post-synaptic membrane. Thus the post-synaptic membrane does not get depolarised, so Ca ion channels don't open, so Ca ions don't move in, so Troponin does not move Tropomyosin and actinmyosin complex can't form, so muscles cannot contract.