When 1.00 mol dm–3 solutions of salicylic acid and sodium hydroxide are mixed a buffer solution can be formed. Salicylic acid is a monoprotic acid that can be represented by the formula HA.
(a) Select a mixture from the table below that would produce a buffer solution.
Mixture vol. salicylic acid/cm3 vol. sodium hydroxide/cm3
X 25 75
Y 50 50
Z 75 25
The mark scheme states the answer as 'Z' with the reason being 'The idea that the solution contains both HA and A−'
Can someone please explain I don't understand this answer