The Student Room Group

AS Chem - Intermolecular forces

Can anyone help me with the following q's please:

1. In terms of the intermolecular forces involved suggest why hydrogen iodide requires more heat energy for melting than hydrogen chloride does.

2.Explain why the heat energy required to melt sodium chloride is large.

3.The heat energy needed to vaporise one mole of sodium chloride is much greater than the heat energy required to melt one mole of sodium chloride. Explain why this is so.

4.In terms of its structure and bonding suggest why graphite has a very high melting point.

Thanks
Reply 1
:frown:
Reply 2
thelibertines

1. In terms of the intermolecular forces involved suggest why hydrogen iodide requires more heat energy for melting than hydrogen chloride does.


Iodine is less electronegative, so there will be less distortion in the bond, and the bond will be stronger meaning more energy is needed to break it.
Reply 3
thelibertines

2.Explain why the heat energy required to melt sodium chloride is large.
/QUOTE]

Sodium chloride is a large ionic structure. Ionic bonda are strong and so lots of energy is needed to break them, which is what is required to melt it.
Reply 4
thelibertines
3.The heat energy needed to vaporise one mole of sodium chloride is much greater than the heat energy required to melt one mole of sodium chloride. Explain why this is so.


as well as melting it, the energy required to vapourise it must break ALL bonds, whereas melting it only breaks the structure and leave a liquid form (where there are some bonds)

I guess?
Reply 5
Ah right, that all makes sense actually! Thankyou so much :biggrin:
Reply 6
thelibertines

4.In terms of its structure and bonding suggest why graphite has a very high melting point.


Each carbon atom is covelantly bonded to three other carbon atoms and has a van der waals bond with a fourth. so to melt it all these strong bonda must be broken. this requires lots of energy.
Reply 7
mik1a
Iodine is less electronegative, so there will be less distortion in the bond, and the bond will be stronger meaning more energy is needed to break it.


No I dont think that's right.

I think it's to do with as you go down group 7 the atomic radius increases, so the forces of attraction to the outer shell electron decreases.
Reply 8
thelibertines
Can anyone help me with the following q's please:

1. In terms of the intermolecular forces involved suggest why hydrogen iodide requires more heat energy for melting than hydrogen chloride does.

2.Explain why the heat energy required to melt sodium chloride is large.

3.The heat energy needed to vaporise one mole of sodium chloride is much greater than the heat energy required to melt one mole of sodium chloride. Explain why this is so.

4.In terms of its structure and bonding suggest why graphite has a very high melting point.

Thanks

2. Sodium chloride has strong (ionic) electrostatic attractions between the cations and anions

3. I think it is harder to vaporise because sodium chloride is soluble in water as it's able to form hydrogen bonds which are the strongest form of intermolecular forces.

4. Graphite has strong covalent bonds as well as the intermolecular forces of instantaneous (or induced) dipole- instantaneous dipole attractions between 'sheets' of carbon atoms.
Reply 9
hihihihi
2. Sodium chloride has strong (ionic) electrostatic attractions between the cations and anions

3. I think it is harder to vaporise because sodium chloride is soluble in water as it's able to form hydrogen bonds which are the strongest form of intermolecular forces.

4. Graphite has strong covalent bonds as well as the intermolecular forces of instantaneous (or induced) dipole- instantaneous dipole attractions between 'sheets' of carbon atoms.


Thankyou! By the way is instantaneous dipole-dipole attraction the same as van der Waals or not?
Reply 10
thelibertines
By the way is instantaneous dipole-dipole attraction the same as van der Waals or not?

Yes, and same as 'London forces' too!