The Student Room Group

Iodine clock reaction-equation?

hey, does anyone know the equation for iodine clock reaction? ive searched the internet but i think my reactants are slightly different to the normal ones

I used:
Potassium peroxydisulfate
Potassium iodide
sodium thiosulphate
starch solution

but thats all i can tell you because i dont even know the products! im having a really blank day.....

if anyone could help i would really appreciate it thankyou!
Reply 1
First the iodide ions react with the peroxydisulfate ions to produce iodine: 2I+S2O8 2I2+2SO4 22I^- + S_2O_8 \ ^{2-} \rightarrow I_2 + 2SO_4 \ ^{2-} , but then the iodine is turned back into iodide ions by the sodium thiosulfate: I2+2S2O3 22I+S4O6 2I_2 + 2S_2O_3 \ ^{2-} \rightarrow 2I^- + S_4O_6 \ ^{2-} . Once the thiosulfate runs out, the I2I_2 iodine then reacts with the starch and turns the solution a dark blue/black colour.
Reply 2
Kolya
First the iodide ions react with the peroxydisulfate ions to produce iodine: 2I+S2O8 2I2+2SO4 22I^- + S_2O_8 \ ^{2-} \rightarrow I_2 + 2SO_4 \ ^{2-} , but then the iodine is turned back into iodide ions by the sodium thiosulfate: I2+2S2O3 22I+S4O6 2I_2 + 2S_2O_3 \ ^{2-} \rightarrow 2I^- + S_4O_6 \ ^{2-} . Once the thiosulfate runs out, the I2I_2 iodine then reacts with the starch and turns the solution a dark blue/black colour.

thankyou thankyou thankyou!
Reply 3
I am doing my chemistry coursework and used the same chemicals, is the equation above definitely correct?
I used starch solution
Potassium iodide
Potassium peroxidisulfate
sodium thiosulfate

When I looked online many people have done the iodine clock reaction differently.....
whats the colours of I- and I2 in the 2nd equation?
Reply 5
Iodide anions are colorless, iodine is yellow to brown.