I suspect that a lot of the skills you'll want to mention will be common to both areas so in that sense it's not a problem, just might look a bit weird that you either
a) don't mention what area you're applying for (i.e. no "Nursing" or "Midwife")
b) mention one on an application for the other
Perhaps honesty is the best policy, although you could lay yourself open to questions about how certian you are that it's the career you want to pursue. Perhaps you could say that you're reservign judgement subject to some more work experience you've got lined up.
IMO it's a tricky one