Each Chlorine atom either has a mass number of 35 or 37, and there are 3 chlorine atoms in ICl3. So find out all the different combinations of chlorine isotopes in ICL3, the different combinations of isotopes cause ICl3 to have many mass numbers. The peak in the mass spectrum is the mass/charge ratio, and the charge of the ion is 1, so different mass numbers of ICL+3 produce different peaks in its mass spectrum.
Combinations of ICL3:
- Iodine (127) + Chlorine (35) + Chlorine (35) + Chlorine (35) = mass 232
- Iodine (127) + Chlorine (37) + Chlorine (35) + Chlorine (35) = mass 234
- Iodine (127) + Chlorine (37) + Chlorine (37) + Chlorine (35) = mass 236
- Iodine (127) + Chlorine (37) + Chlorine (37) + Chlorine (37) = mass 238
There are only 4 different combinations of chlorine isotopes in ICL3, so there is only 4 mass peaks, this means that the correct answer is C.